š Awarded For: Their pioneering work in the creation and development of MetalāOrganic Frameworks (MOFs) ā a new class of crystalline porous materials with extraordinary tunability and surface area.
š¬ What Are MetalāOrganic Frameworks (MOFs)?
MOFs are hybrid materials made by linking metal ions or clusters with organic ligands (molecules containing carbon). Think of them as 3D networks built from metal nodes and organic connectors ā like a molecular scaffold.
Each MOF structure looks like a sponge at the nanoscale ā full of tiny, uniform pores that can trap and release specific molecules.
āļø Basic Structure:
Metal centers: act as coordination nodes (e.g., Zn²āŗ, Cu²āŗ, Al³āŗ, etc.)
Organic linkers: act as bridges (e.g., terephthalic acid, imidazolate, etc.)
Together they form a porous lattice that can be precisely engineered for size, shape, and functionality.
š¬ļø Key Scientific Properties:
Ultra-high surface area: Some MOFs have over 7000 m²/g, greater than any other known material! (For comparison: one gram of MOF can cover a football field.)
Tunable porosity: The pore size and chemistry can be tailored ā enabling selective adsorption of gases or molecules.
Reversible adsorption/desorption: MOFs can ābreatheā ā taking in or releasing gases without structural collapse.
Thermal and chemical stability: Many modern MOFs remain stable under high temperature and humidity, making them industrially viable.
āļø Major Applications:
Carbon Capture & Storage (CCS): MOFs selectively trap COā from industrial emissions ā vital for combating climate change.
Hydrogen & Methane Storage: They can store hydrogen fuel at low pressures, enabling clean energy systems.
Catalysis: MOFs act as nano-reactors where chemical reactions can be precisely controlled.
Drug Delivery: Their tunable pore size allows controlled release of pharmaceutical molecules.
Water Harvesting & Purification: Certain MOFs can extract moisture directly from desert air ā converting humidity into clean water.
1990s: Richard Robson and Susumu Kitagawa independently demonstrated metalāorganic coordination polymers.
1995: Omar Yaghi coined the term āMetalāOrganic Frameworkā and designed MOF-5 ā the prototype that revolutionized the field.
2000sāpresent: Thousands of MOF structures synthesized with tunable geometry and function ā an entirely new branch of materials chemistry.
š Scientific Impact:
MOFs have bridged coordination chemistry, solid-state physics, and nanotechnology, becoming essential for sustainable energy, environmental engineering, and molecular storage systems.
Their discovery represents one of the most versatile and powerful tools in modern materials science.
š§ Summary:
AspectDescriptionMaterial TypePorous crystalline coordination networkComponentsMetal nodes + organic linkersInventorsKitagawa, Robson, YaghiUnique PropertyHighest surface area per gramApplicationsGas storage, catalysis, drug delivery, water harvestingScientific ValueMolecular-level control over porosity and chemistry
š¬ Final Note: The 2025 Nobel Prize recognizes not just a discovery ā but the creation of a new material universe where atoms are arranged by design, not chance. MetalāOrganic Frameworks are the architecture of the molecular future. š§±āØ
SHANTI CLASSES ME GATE ESE +
šļø NOBEL PRIZE 2025 ā CHEMISTRY š§Ŗ
š Laureates:
Susumu Kitagawa (Japan)
Richard Robson (Australia)
Omar M. Yaghi (USA)
š Awarded For:
Their pioneering work in the creation and development of MetalāOrganic Frameworks (MOFs) ā a new class of crystalline porous materials with extraordinary tunability and surface area.
š¬ What Are MetalāOrganic Frameworks (MOFs)?
MOFs are hybrid materials made by linking metal ions or clusters with organic ligands (molecules containing carbon).
Think of them as 3D networks built from metal nodes and organic connectors ā like a molecular scaffold.
Each MOF structure looks like a sponge at the nanoscale ā full of tiny, uniform pores that can trap and release specific molecules.
āļø Basic Structure:
Metal centers: act as coordination nodes (e.g., Zn²āŗ, Cu²āŗ, Al³āŗ, etc.)
Organic linkers: act as bridges (e.g., terephthalic acid, imidazolate, etc.)
Together they form a porous lattice that can be precisely engineered for size, shape, and functionality.
š¬ļø Key Scientific Properties:
Ultra-high surface area:
Some MOFs have over 7000 m²/g, greater than any other known material!
(For comparison: one gram of MOF can cover a football field.)
Tunable porosity:
The pore size and chemistry can be tailored ā enabling selective adsorption of gases or molecules.
Reversible adsorption/desorption:
MOFs can ābreatheā ā taking in or releasing gases without structural collapse.
Thermal and chemical stability:
Many modern MOFs remain stable under high temperature and humidity, making them industrially viable.
āļø Major Applications:
Carbon Capture & Storage (CCS):
MOFs selectively trap COā from industrial emissions ā vital for combating climate change.
Hydrogen & Methane Storage:
They can store hydrogen fuel at low pressures, enabling clean energy systems.
Catalysis:
MOFs act as nano-reactors where chemical reactions can be precisely controlled.
Drug Delivery:
Their tunable pore size allows controlled release of pharmaceutical molecules.
Water Harvesting & Purification:
Certain MOFs can extract moisture directly from desert air ā converting humidity into clean water.
š§© Historical Milestones:
1990s:
Richard Robson and Susumu Kitagawa independently demonstrated metalāorganic coordination polymers.
1995:
Omar Yaghi coined the term āMetalāOrganic Frameworkā and designed MOF-5 ā the prototype that revolutionized the field.
2000sāpresent:
Thousands of MOF structures synthesized with tunable geometry and function ā an entirely new branch of materials chemistry.
š Scientific Impact:
MOFs have bridged coordination chemistry, solid-state physics, and nanotechnology, becoming essential for sustainable energy, environmental engineering, and molecular storage systems.
Their discovery represents one of the most versatile and powerful tools in modern materials science.
š§ Summary:
AspectDescriptionMaterial TypePorous crystalline coordination networkComponentsMetal nodes + organic linkersInventorsKitagawa, Robson, YaghiUnique PropertyHighest surface area per gramApplicationsGas storage, catalysis, drug delivery, water harvestingScientific ValueMolecular-level control over porosity and chemistry
š¬ Final Note:
The 2025 Nobel Prize recognizes not just a discovery ā but the creation of a new material universe where atoms are arranged by design, not chance.
MetalāOrganic Frameworks are the architecture of the molecular future. š§±āØ
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